@Article{JAMS-2-2, author = {Scardino, Jo, Debra and McDowell, Matthew, D. and Jacob, Graham, D. and Nathan, I., Hammer}, title = {The Multiphoton Ionization Spectrum of Methyl Iodide Revisited: 1.67-2.2 ev Excitation}, journal = {Journal of Atomic and Molecular Sciences}, year = {2011}, volume = {2}, number = {2}, pages = {93--98}, abstract = {

The study of the multiphoton ionization of methyl iodide has a long and storied history. Here, we revisit this topic and present spectra of each of the photoionization and photodissociation fragments ($C^{+},$ $CH^{+},$ $CH_{2}^{+},$ $CH_{3}^{+},$ $CH_{3}I^{+},$ and $I^{+}$) using a custom time-of-flight mass spectrometer and a tunable dye laser over the excitation range of 550-740 nm (2.2-1.67 eV). The choice of this wavelength range allows for excitation through the $A$ state and resonant ionization through higher energy levels using 4+1, 5+1, or 6+1 photons for excitation and ionization.  Although the various fragments yield very similar spectra, fewer fragment ions are observed with increasing wavelength.

}, issn = {2079-7346}, doi = {https://doi.org/10.4208/jams.010511.011411a}, url = {https://global-sci.com/article/74403/the-multiphoton-ionization-spectrum-of-methyl-iodide-revisited-167-22-ev-excitation} }