Structural Properties of $Rh_n (n=2$∼$100)$ Clusters by Using Gupta Potential with the Simulation of Quenching Method

Structural Properties of $Rh_n (n=2$∼$100)$ Clusters by Using Gupta Potential with the Simulation of Quenching Method

Year:    2013

Author:    Mailitan Kailaimu, Chun-Li Li, Hai-Ming Duan

Journal of Atomic and Molecular Sciences, Vol. 4 (2013), Iss. 3 : pp. 235–244

Abstract

The ground-state geometries and energies of $Rh_n (n=2$∼$100)$ clusters are investigated by using Gupta potential combined with the molecular dynamics simulated quenching method and the genetic algorithm. Our results show that: As comparing the lowest energy structure obtained from the simulated quenching method which can be regarded as the ground-state structure, almost all these ground-state geometries can be found (except $Rh_{50})$ by using the genetic algorithm for clusters containing 60 or less atoms, but the efficiency of capturing the ground-state geometry decreases obviously with increasing the cluster size. The effective temperature range for obtaining the ground-state energy (geometry) is obtained by systematically analyzing the energy distributions of the simulated quenching structures, and the correlation between the quenching method of finding the ground-state and the cluster size is also investigated further.

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Journal Article Details

Publisher Name:    Global Science Press

Language:    English

DOI:    https://doi.org/10.4208/jams.102312.112412a

Journal of Atomic and Molecular Sciences, Vol. 4 (2013), Iss. 3 : pp. 235–244

Published online:    2013-01

AMS Subject Headings:    Global Science Press

Copyright:    COPYRIGHT: © Global Science Press

Pages:    10

Keywords:    Gupta potential cluster ground-state molecular dynamics simulated quenching.

Author Details

Mailitan Kailaimu

Chun-Li Li

Hai-Ming Duan