Controlling the Molecular Rotational Wave Packet Accurately by Femtosecond Laser Pulses

Controlling the Molecular Rotational Wave Packet Accurately by Femtosecond Laser Pulses

Year:    2011

Author:    Zeng-Qiang Yang, Jian-Jun Zhang, Yan-Wen Zhang

Journal of Atomic and Molecular Sciences, Vol. 2 (2011), Iss. 2 : pp. 143–154

Abstract

We investigate the rotational wave packet modified by femtosecond laser pulses. The calculations are performed by solving numerically the full time-dependent Schrödinger equation for the $N_2$ molecule at finite rotational temperature. It is demonstrated that the rotational wave packet induced by the first laser pulse can be controlled exactly just by selecting the optimal time at which the second laser pulse is introduced. Whether the pulse duration of the two lasers is equal or not, the molecular alignment induced by the first laser pulse can be enhanced or degraded by precisely inserting the peak of the second laser pulse at the maximum or minimum position of the slope curve for the alignment parameter by the first laser. Furthermore, the already enhanced alignment by the two lasers can be enhanced or degraded by precisely inserting the peak of the third laser at the maximum or minimum position of the slope curve for the alignment by the two lasers. The already degraded alignment by the two lasers can be increased again from the isotropic distributed ensemble by precisely inserting the peak of the third laser at the peak position of the slope curve by the two lasers.

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Journal Article Details

Publisher Name:    Global Science Press

Language:    English

DOI:    https://doi.org/10.4208/jams.070510.073010a

Journal of Atomic and Molecular Sciences, Vol. 2 (2011), Iss. 2 : pp. 143–154

Published online:    2011-01

AMS Subject Headings:    Global Science Press

Copyright:    COPYRIGHT: © Global Science Press

Pages:    12

Keywords:    rotational wave packets femtosecond laser pulses time delay the slope curve for the alignment.

Author Details

Zeng-Qiang Yang

Jian-Jun Zhang

Yan-Wen Zhang