Year: 2011
Journal of Fiber Bioengineering and Informatics, Vol. 4 (2011), Iss. 3 : pp. 209–219
Abstract
Textile wet processing is the most polluting aspect of textile manufacturing and contributes to the global textile industry's substantial carbon footprint. Textile preparation of cotton typically includes scouring and bleaching at high temperature and high pH. Substantial amounts of wastewater are produced that must be treated prior to being released to receiving fresh water. Recent research in our laboratories has focused on the development and application of compounds that enhance the bleaching process. We have developed novel cationic bleach activators that can be used to bleach cellulosic fabrics and fiber blends at reduced temperature, pH, and time. Results show that after optimization equivalent or improved performance in whiteness, absorbency and strength are possible relative to conventional bleaching methods. One of the most promising bleach activators to date is N-[4-(Triethylammoniomethyl) Benzoyl]-Butyrolactam Chloride (TBBC). TBBC was designed in our group to a) exhibit strong oxidation potential when activated; b) have reasonable hydrolytic stability; and c) be inherently substantive towards cellulosic and other fibers. In this paper, we review the development of bleach activators for textile bleaching, and discuss the opportunities and potential hurdles involved in commercialization of bleach activators for textile wet processing.
You do not have full access to this article.
Already a Subscriber? Sign in as an individual or via your institution
Journal Article Details
Publisher Name: Global Science Press
Language: English
DOI: https://doi.org/10.3993/jfbi09201101
Journal of Fiber Bioengineering and Informatics, Vol. 4 (2011), Iss. 3 : pp. 209–219
Published online: 2011-01
AMS Subject Headings:
Copyright: COPYRIGHT: © Global Science Press
Pages: 11
Keywords: Bleaching
-
Synthesis of a Novel and More Sustainable Cationic Bleach Activator, N-[4-(N,N,N)-Triethylammoniumchloride-butanoyl] Butyrolactam, for Cotton: Optimization and Theoretical Limitations
Altay, Pelin | Yıldırım, Erol | Gürsoy, Nevin Çiğdem | Hauser, Peter J. | El-Shafei, AhmedACS Sustainable Chemistry & Engineering, Vol. 10 (2022), Iss. 14 P.4415
https://doi.org/10.1021/acssuschemeng.1c07233 [Citations: 2] -
Tri-nuclear phthalocyanine complexes carrying N/O donor ligands as hydrogen peroxide catalysts, and their bleaching activity measurements by an online spectrophotometric method
Sen, Pinar | Dege, Necmi | Yildiz, S. ZekiJournal of Coordination Chemistry, Vol. 70 (2017), Iss. 16 P.2751
https://doi.org/10.1080/00958972.2017.1360490 [Citations: 12] -
Green Chemistry for Sustainable Textiles
Environmentally sound textile wet processing
Gürses, Ahmet | Güneş, Kübra | Şahin, Elif2021
https://doi.org/10.1016/B978-0-323-85204-3.00008-7 [Citations: 4] -
Energy-Saving One-Step Pre-Treatment Using an Activated Sodium Percarbonate System and Its Bleaching Mechanism for Cotton Fabric
Li, Qing | Lu, Run | Liang, Yan | Gao, Kang | Jiang, HuiyuMaterials, Vol. 15 (2022), Iss. 17 P.5849
https://doi.org/10.3390/ma15175849 [Citations: 2] -
Improving the Wettability of Enzyme-Bleached Cotton Fabric with Inclusion of Sodium Surfactin
Farrell, Matthew J. | De Boskey, Miranda J. | Ankeny, Mary A.ACS Sustainable Chemistry & Engineering, Vol. 4 (2016), Iss. 3 P.1569
https://doi.org/10.1021/acssuschemeng.5b01486 [Citations: 7] -
New alkaline media-soluble functional zinc(II) phthalocyanines bearing poly (hydroxylmethyl)iminomethane Schiff base complexes in catalytic bleaching
Sen, Pinar | Yildirim, Ertug | Yildiz, S. ZekiSynthetic Metals, Vol. 215 (2016), Iss. P.41
https://doi.org/10.1016/j.synthmet.2016.01.020 [Citations: 12] -
Combinative Scouring, Bleaching, and Cationization Pretreatment of Greige Knitted Cotton Fabrics for Facilely Achieving Salt-Free Reactive Dyeing
Ma, Wei | Shen, Kezhan | Xiang, Nan | Zhang, ShufenMolecules, Vol. 22 (2017), Iss. 12 P.2235
https://doi.org/10.3390/molecules22122235 [Citations: 20] -
Efficient and sustainable bleaching of cotton/spandex integrating UVA radiation and peroxide activator: A study focus on the degradation mechanism of natural pigments in fibres
Li, Qing | Lu, Run | Jiang, Huiyu | Zhou, YuyangArabian Journal of Chemistry, Vol. 16 (2023), Iss. 12 P.105348
https://doi.org/10.1016/j.arabjc.2023.105348 [Citations: 1] -
The use of hydrogen peroxide and sky stabilizer agent in bleaching process of textile fabrics
Khaliq, Ab Dulmalik | Chafidz, Achmad | Maddun, Faisal Rasjid | Herimawan, Hafizh Rafi | Yusuf, Ghalib Muhammad | Rahmillah, Fety IlmaTHE 4TH INNOVATION AND ANALYTICS CONFERENCE & EXHIBITION (IACE 2019), (2019), P.050011
https://doi.org/10.1063/1.5121116 [Citations: 2] -
Functional zinc(II) phthalocyanines bearing Schiff base complexes as oxidation catalysts for bleaching systems
Sen, Pinar | Kara Simsek, Dilek | Yildiz, S. ZekiApplied Organometallic Chemistry, Vol. 29 (2015), Iss. 8 P.509
https://doi.org/10.1002/aoc.3324 [Citations: 17] -
Nanofinishing of Textile Materials
Nanobleaching
Montazer, Majid | Harifi, Tina2018
https://doi.org/10.1016/B978-0-08-101214-7.00004-2 [Citations: 1] -
Low Temperature Bleaching of Cotton with a Novel Cationic Activator
Li, Yan Li | Liu, Zhen Dong | Wang, Xiao NingAdvanced Materials Research, Vol. 608-609 (2012), Iss. P.1391
https://doi.org/10.4028/www.scientific.net/AMR.608-609.1391 [Citations: 0] -
Low temperature bleaching for reactive dyeing and top white knitted cotton fabric
Bulut, Meliha Oktav
Journal of Cleaner Production, Vol. 137 (2016), Iss. P.461
https://doi.org/10.1016/j.jclepro.2016.07.124 [Citations: 15] -
Low-temperature bleaching of knit fabric from regenerated bamboo fibers with different peracetic acid bleaching processes
Špička, Nina | Tavčer, Petra ForteTextile Research Journal, Vol. 85 (2015), Iss. 14 P.1497
https://doi.org/10.1177/0040517514563728 [Citations: 16] -
Natural Dyes for Sustainable Textiles
Sustainability and its significance in textile wet processing
Vankar, Padma Shree | Shukla, Dhara2024
https://doi.org/10.1016/B978-0-323-85257-9.00005-0 [Citations: 0] -
Substituted manganese phthalocyanines as bleach catalysts: synthesis, characterization and the investigation of de-aggregation behavior with LiCl in solutions
Sen, Pinar | Zeki Yildiz, S.Research on Chemical Intermediates, Vol. 45 (2019), Iss. 2 P.687
https://doi.org/10.1007/s11164-018-3637-0 [Citations: 5] -
Boosting alkaline photocatalytic H2O2 generation by incorporating pyrophosphate on g-C3N4 for effective proton shuttle and oxygen activation
Xu, Liangpang | Li, Lejing | Hu, Zhuofeng | Yu, Jimmy C.Applied Catalysis B: Environmental, Vol. 328 (2023), Iss. P.122490
https://doi.org/10.1016/j.apcatb.2023.122490 [Citations: 36] -
Establishing an ultrasound-assisted activated peroxide system for efficient and sustainable scouring-bleaching of cotton/spandex fabric
Li, Qing | Ni, Lijie | Wang, Jiacheng | Quan, Heng | Zhou, YuyangUltrasonics Sonochemistry, Vol. 68 (2020), Iss. P.105220
https://doi.org/10.1016/j.ultsonch.2020.105220 [Citations: 23] -
Establishing an energy-saving scouring/bleaching one-step process for cotton/spandex fabric using UVA-assisted irradiation
Li, Qing | Zhao, Xiaowei | Quan, Heng | Zhou, YuyangRSC Advances, Vol. 12 (2022), Iss. 15 P.9404
https://doi.org/10.1039/D2RA00659F [Citations: 6] -
Novel bleach activator compounds derived from the reaction of isocyanic acid with selected nucleophiles
Lewis, David M. | Hawkes, Jamie A.Coloration Technology, Vol. 139 (2023), Iss. 4 P.355
https://doi.org/10.1111/cote.12662 [Citations: 0]