Year: 2017
Author: Tian Ma, Shouhong Wang
Journal of Mathematical Study, Vol. 50 (2017), Iss. 3 : pp. 215–241
Abstract
The main objectives of this paper are five-fold. The first is to introduce a general dynamic law for all physical motion systems, based on a new variational principle with constraint-infinitesimals. The second is to postulate the potential-descending principle (PDP). We show that PDP is a more fundamental principle than the first and second laws in thermodynamics, and gives rise to dynamical equations for non-equilibrium systems. The third is to demonstrate that the PDP is the first principle to describe irreversibility of all thermodynamic systems, with thermodynamic potential as the basic physical quantity, rather than entropy. The fourth objective is to examine the problems faced by the Boltzmann equation. We show that the Boltzmann is not a physical law, is created as a mathematical model to obey the entropy-increasing principle (for dilute gases), and consequently is unable to faithfully describe Nature. The fifth objective is to prove an orthogonal-decomposition theorem and a theorem on variation with constraint-infinitesimals, providing the needed mathematical foundations of the dynamical law of physical motion.
Journal Article Details
Publisher Name: Global Science Press
Language: English
DOI: https://doi.org/10.4208/jms.v50n3.17.02
Journal of Mathematical Study, Vol. 50 (2017), Iss. 3 : pp. 215–241
Published online: 2017-01
AMS Subject Headings:
Copyright: COPYRIGHT: © Global Science Press
Pages: 27
Keywords: Dynamical law of physical motion potential-descending principle statistical physics thermodynamics entropy irreversible processes Boltzmann equation orthogonal-decomposition theorem variation with constraint-infinitesimals.