An Implicit Solver for the Time-Dependent Kohn-Sham Equation

Year:    2021

Author:    Zhicheng Hu, Lei Yang, Guanghui Hu, Yedan Shen, Zhicheng Hu, Guanghui Hu

Numerical Mathematics: Theory, Methods and Applications, Vol. 14 (2021), Iss. 1 : pp. 261–284

Abstract

The implicit numerical methods have the advantages on preserving the physical properties of the quantum system when solving the time-dependent Kohn-Sham equation. However, the efficiency issue prevents the practical applications of those implicit methods. In this paper, an implicit solver based on a class of Runge-Kutta methods and the finite element method is proposed for the time-dependent Kohn-Sham equation. The efficiency issue is partially resolved by three approaches, i.e., an $h$-adaptive mesh method is proposed to effectively restrain the size of the discretized problem, a complex-valued algebraic multigrid solver is developed for efficiently solving the derived linear system from the implicit discretization, as well as the OpenMP based parallelization of the algorithm. The numerical convergence, the ability on preserving the physical properties, and the efficiency of the proposed numerical method are demonstrated by a number of numerical experiments.

Journal Article Details

Publisher Name:    Global Science Press

Language:    English

DOI:    https://doi.org/10.4208/nmtma.OA-2020-0040

Numerical Mathematics: Theory, Methods and Applications, Vol. 14 (2021), Iss. 1 : pp. 261–284

Published online:    2021-01

AMS Subject Headings:   

Copyright:    COPYRIGHT: © Global Science Press

Pages:    24

Keywords:    Time-dependent Kohn-Sham equation implicit midpoint scheme finite element methods h-adaptive mesh methods complex-valued algebraic multigrid methods.

Author Details

Zhicheng Hu

Lei Yang

Guanghui Hu

Yedan Shen

Zhicheng Hu

Guanghui Hu